The mechanochemical stochastic processes of molecular motors

In this article, we develop a rigorous mathematical foundation of microscopic motors. The main characteristic is the combination of Brownian and Poisson noises.     

水火箭的制作与发射——初中物理教学课外活动拓展

物理课外实验能让学生真正动手操作、体验,从而提高学生的物理核心素养.水火箭的制作与发射,蕴含知识面广,发射效果震撼,能让学生对物理与科技的联系有直观深刻的认识.     

A canonical treatment of nonautonomous systems of type\dot \upsilon = f(t) + c.

We solve by canonical methods, the Hamilton-Jacobi equation and the Poisson bracket technique, the special type of nonautonomous systems described by the equation . The general expressions so obtained are applied to the free rocket and the rocket in a uniform gravitational field, which serve as illustrations and test of the general results.     

含人工脱粘层固体装药结构应力应变场分析

针对某翼柱型固体装药结构,选取1/16子结构进行了有限元分析。通过将其分割成若干具有单一拓扑型式的组合体,获得了精度较高的结构化网格。在三维线性粘弹性理论和边界非线性理论基础上,基于接触算法模拟了人工脱粘层的边界条件;研究了固化降温过程含人工脱粘层固体装药结构的变形特征和应变场,并与无人工脱粘层的计算结果进行了对比,结果表明:人工脱粘层可以显著地改善固体装药结构端部的应变水平,最大的等效VonMises应变从无人工脱粘的30.1%下降为23.0%。此外,探讨了人工脱粘层前缘的应力水平以及工程上界面脱粘的快速近似计算方法。     

惯导系统火箭撬试验数据处理方法

惯导系统火箭橇试验技术在国内还属于一门新兴的试验技术,刚处于起步探索阶段。惯导系统火箭橇试验是验证惯导系统在复合环境下的误差模型、评定制导系统误差模型精度以及分离大过载条件下惯导系统误差系数的有效手段。主要探讨了惯导系统的误差模型,提出了基于火箭橇试验的动态条件下的误差分离和数据处理方案,并对火箭橇试验中数据处理方法进行了分析。这些研究为在我国进一步开展惯性装置火箭橇试验研究提供理论基础。     

多目标多光谱辐射高速高温计的研制

固体火箭羽焰是一种特殊的火焰,固体火箭发动机喷管羽流沿径向和轴向的温度是研究固体推进剂燃烧状况和发动机燃烧流场的基本参数。针对固体火箭发动机尾喷焰温度及其空间分布测量的需要,继1999年采用多光谱辐射测温方法和技术实现航天某型号固体火箭发动机测量后,研制了新型的多目标多光谱辐射高速高温计用于固体火箭发动机地面搭载试验。仪器使用组合棱镜和光电二极管阵列实现目标0.4~1.1μm光谱的热辐射测量,在主光路设计中首次使用光纤技术,实现一台仪器同时测量空间分布6个目标点的温度和发射率,每个点的空间位置由光阑上的通光孔精确确定,且每个目标测点均有8个工作光谱,研制的同步高速数据采集系统完成48个测量通道的数据同步时间小于10 ns。     

液体火箭发动机中声腔抑制不稳定燃烧的声学分析

发展了声腔的分析和数值模型,对液体火箭发动机不稳定燃烧的抑制作用进行了评定,通过迭代计算研究了二维流动和温度分布变化对声腔调 谐和稳定性能的影响,对不同的声腔几何尺寸和温度梯度的稳定性计算结果表明,燃烧带有较大开口面积的声腔会更大程度地改变振荡的空间分布,这种改变而且影响了驱动和抑制燃烧的机理,讨论了在声腔设计安排中正确选择声腔的几何尺寸,且比较了不同长度和不同直径声腔的阻尼特性,通过考察声吸收系统的方法来最优化系统的阻尼,得到了可供设计参考的结论。     

Molecular switching on surfaces

Molecular switching has established itself as a key functionality of building blocks developed for addressable materials and surfaces over the last two decades. Many challenges in their use and characterisation have been presented by the wide variation in interfaces studied, these ranging from truly single-molecule devices to two-dimensional self-assembled monolayers and thin films that bridge the gap between surface and macroscopically bulk materials (polymers, MOFs, COFs), and further still to other interfaces (solid–liquid, liquid–air, etc.). The low number density of molecules on monolayer-coated interfaces as well as in thin films, for example, presents substantial challenges in the characterisation of the composition of modified interfaces. The switching of molecular structure with external stimuli such as light and electrode potential adds a further layer of complexity in the characterisation of function. Such characterisation “in action” is necessary to correlate macroscopic phenomena with changes in molecular structure. In this review, key classes of molecular switches that have been applied frequently to interfaces will be discussed in the context of the techniques and approaches used for their operando characterisation. In particular, we will address issues surrounding the non-innocence of otherwise information-rich techniques and show how model – non-switching – compounds are often helpful in confirming and understanding the limitations and quirks of specific techniques.     

Motion of Enzyme‐Powered Microshell Motors

Microshells are attractive in constructing bubble‐propelled micromotors due to the lower energy consumption for bubbles forming on a concave surface. In this work, enzyme‐powered microshell motors were fabricated on multimetallic (Au/Ag/Au) microshells along with the modification of catalase on its concave surface. The catalase triggered the decomposition of hydrogen peroxide to oxygen gas, hence propelling the autonomous motion of microshell motors. A size‐dependent motion behaviour was observed for the microshell motors in the form of slow tremble and fast translation motion for a size smaller and larger than 5 μm, respectively, according to the size, generation efficiency and ejection mechanism of bubbles and the intensity of Brownian motion. In addition, the effect of fuel concentration on the motion speed of microshells was dependent on whether the bubble generation was affected by the limited mass transfer in the microshell space. These findings play an important role for the design of microshell motors.